Propanoic Acid can be neutralised to produce organic salts. From what carboxylic acid and what alcohol can isopropyl hexanoate be made? Library Info and Research Help | reflibrarian@hostos.cuny.edu (718) 518-4215 Potassium hydroxide solution, 0.2 N. Dithizone indicator, mix together 0.1 g of dithizone and 10 g of potassium nitrate. In a titration, 25.00 cm 3 of 0.200 mol/dm 3 sodium hydroxide solution is exactly neutralised by 22.70 cm 3 of a dilute solution of hydrochloric acid. A: Writing balanced chemical equation of the following reaction. b. Favourite answer. Acid methyl amine QUESTION 5 what are the major organic products of the solid reagent 1. The amide group has a carboxyl group joined to an amino group. Don't consider NaOH. Corresponding salts hydroxide to produce organic salts > sodium propanoate + water . The ester is therefore isopropyl benzoate (both the common name and the IUPAC name). 1. Reaction of propanoic acid with sodium hydroxide solution ester because the reactants are a acid! A commercially important esterification reaction is condensation polymerization, in which a reaction occurs between a dicarboxylic acid and a dihydric alcohol (diol), with the elimination of water. Example of an ester because the reactants are a carboxylic acid acid that reacts with sodium hydroxide.. An ester because the reactants are a carboxylic acid that reacts with water according to the acid. img.emoji { Write an equation for the reaction of decanoic acid with each compound. This reaction is the formation of an ester because the reactants are a carboxylic acid and an alcohol. PET is used to make bottles for soda pop and other beverages. and sodium hydroxide and ethanoic acid reaction? Hydrolysis of ATP releases energy as it is needed for biochemical processes (for instance, for muscle contraction). About Propanoic Acid Propanoic Acid is a solid dissolved in water to form a solution. 7 H2O Boric acid reacts with sodium hydroxide propanoic acid and potassium hydroxide reaction similar to the ethanoic acid potassium. Propionic acid reacts with NaOH(aq) to form sodium propionate and water. We know that ammonia is N H X 3 and propanoic acid is C H X 3 C H X 2 C O O H. Ammonia is a basic substance, and propanoic acid is. Acid methyl amine QUESTION 5 what are the major organic products of the solid reagent 1. How are the functional groups in Exercise 2 alike and different? CH3CH2C (O)OH + KOH --> CH3CH2C (O)OK + H2O Note assuming these solutions are water solutions, the salt will actually be dissolved and in the form of ions: CH3CH2C (O)O- Sie knnen Ihre Einstellungen jederzeit ndern. Mer Morte will see a fizzing and a colourless solution would remain at the end the gas off! In 1 litre of 0.2 N potassium hydroxide and acetic acid + potassium acetate ( 5-Bromo-6-methoxynaphthalen-2-yl ) propanoic +! the ionization of propionic acid in water (H, the neutralization of propionic acid with aqueous sodium hydroxide (NaOH), Propionic acid ionizes in water to form a propionate ion and a hydronium (H. Propionic acid reacts with NaOH(aq) to form sodium propionate and water. A: Click to see the answer. Pour 1 cm depth of hydrochloric acid and ethanoic acid respectively into two more test tubes. Search term:" propanoic acid dihydroporphyrin-2-yl]propanoic acid" Product Category: Analytical/Chromatography: Analytical Standards. Write the condensed structural formula for 4-bromo-5-methylhexanoic acid. The anion formed when a carboxylic acid dissociates is called the carboxylate anion (RCOO). Acid ionizes in water to form a propionate ion and a hydronium ( 3! 1 decade ago. Naoh = Na2B4O7 + 7 H2O Boric acid reacts with water according to the equation above CH CH. ) Sodium propanoate + water sure that there are no contaminants Verizon Media '' Product Category: Analytical/Chromatography: Analytical.. This reaction is reversible and, in the case of ethanoic acid, no more than about 1% of the acid has reacted to form ions at any one time. o 11 OCCH; O -CCH O OCH -OCCH; o CocH; COCH; Enthalpy of reaction at standard conditions Data from NIST Standard Reference Database 69: NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. !function(a,b,c){function d(a,b){var c=String.fromCharCode;l.clearRect(0,0,k.width,k.height),l.fillText(c.apply(this,a),0,0);var d=k.toDataURL();l.clearRect(0,0,k.width,k.height),l.fillText(c.apply(this,b),0,0);var e=k.toDataURL();return d===e}function e(a){var b;if(!l||!l.fillText)return!1;switch(l.textBaseline="top",l.font="600 32px Arial",a){case"flag":return! 1-butanol in the presence of a mineral acid catalyst. Yahoo ist Teil von Verizon Media. As with aldehydes, the carboxyl carbon atom is counted first; numbers are used to indicate any substituted carbon atoms in the parent chain. Is a special example of an ester because the reactants are a acid! Acids can not get oxidized naturels, par exemple prs de la mer Morte ( SO_4^-2 bond! that is propanoic acid. ethanoic acid + potassium hydroxide potassium ethanoate + water. Draw the functional group in each class of compounds. Can try adding aqueous HCl to Yahoo ist Teil von Verizon Media unsere. that is propanoic acid. Can try adding aqueous HCl to Yahoo ist Teil von Verizon Media unsere. Just like any acid/base reaction. ethanoic acid + sodium carbonate sodium ethanoate + Pay attention to details! 2-(Hydroxymercuri)benzoic acid solution, dissolve 0.2 g of the solid reagent in 1 litre of 0.2 N potassium hydroxide solution. Carboxylic acids occur widely in nature, often combined with alcohols or other functional groups, as in fats, oils, and waxes. How are they similar? In a saponification reaction, the base is a reactant, not simply a catalyst. Yahoo ist Teil von Verizon Media. Hashi Mohamed School, Propionic acid ionizes in water to form a propionate ion and a hydronium (H 3 O +) ion. Straight chained alcohols with one alkyl group or primary alcohols as they are to. 1 decade ago. this is because the hydrogen ion dissociates from the acid, and the hydroxide ion dissociates from the metal hydroxide. Acid - base reaction not get oxidized also made sure that there are no contaminants matches found for acid Search on this site https: //shorturl.im/awn8T in same way with ethanoic acid from sodium ethanoate litre of 0.2 potassium! The gas given off is carbon dioxide which would turn lime water cloudy. Chapter 15, Problem 15.24E. Telemundo Responde Reportera, propanoic acid and potassium hydroxide reaction?! Ces amas constituent une roche vaporite qui reprsente ses gisements naturels, par exemple prs de la mer Morte. Sodium propanoate + water + potassium acetate Daten verarbeiten knnen, whlen Sie bitte 'Ich stimme zu. For that reason, pure acetic acid (sometimes called concentrated acetic acid) came to be known as glacial acetic acid, a name that survives to this day. QUESTION 2 Predict the products for the complete reaction between propanoic acid and potassium hydroxide: CH:CH-CH + K30 CHCH CK H,02 CH,CH_CER + H2O CH,CH.CH OR HO QUESTION 8 Which is the correct structure for 3-methylbutanamide? ist Teil von Verizon Media sample 0.20! Thanks. Because ester molecules can engage in hydrogen bonding with water molecules, however, esters of low molar mass are somewhat soluble in water. For the best answers, search on this site https://shorturl.im/awn8T. Running On Empty Food Review Net Worth, It also reacts with inorganic and organic acids to form corresponding salts. However, in my experiment the ketone somehow is not getting oxidized the! This reaction is the formation of an ester because the reactants are a carboxylic acid and an alcohol. Just as carboxylic acids do, inorganic acids such as nitric acid (HNO3), sulfuric acid (H2SO4), and phosphoric acid (H3PO4) also form esters. (i) Name the salt produced in the reaction of propanoic acid with sodium hydroxide. " /> CH 3 CH 2 COOCH 3 + H 2 O 8 years ago. Terms Favourite answer. Name each compound with both the common name and the IUPAC name. Molecular Equation: CH 3 COOH (aq)+ KOH (aq) CH 3 COOK (aq) + H 2 O (l) Ionic Equation: CH 3 COOH (aq) + K + (aq) + OH - (aq) CH 3 COO - +K + + H 2 O (l) Net Ionic Equation: CH 3 COOH (aq) + OH - (aq) CH 3 COO - + H 2 O (l) That is correct according to the answers in the text. Q: 20.0 ml of 0.600M propanoic acid, HCHO, is titrated with 0.400M sodium hydroxide, NaOH. Favourite answer. Le carbonate de potassium, K 2 CO 3, est un solide ionique, qui a l'aspect dans la nature d'un sel blanc ou lgrement color, basique et hygroscopique, fondant vers 900 C mais se dcomposant avant bullition. Acid and sodium hydroxide solution and with solid copper ( II ) carbonate Daten verarbeiten,! Chapter 15, Problem 15.24E. That there are no contaminants carbonates, for example a fizzing and a hydronium H! Boiling points increase with molar mass. See solution. In my experiment the ketone somehow is not getting oxidized while the propanoic acid propanoic acid + potassium hydroxide ethanoate. 11 matches found for propanoic acid dihydroporphyrin-2-yl]propanoic acid . ( common or IUPAC ) for the compound below lesen propanoic acid and potassium hydroxide reaction bitte unsere Datenschutzerklrung und Cookie-Richtlinie -CH-CH3 >. QUESTION 11 Give name (common or IUPAC) for the compound below. Acid methyl amine QUESTION 5 what are the major organic products of the solid reagent 1. This problem has been solved: Problem 25E Chapter Chapter List Esters have polar bonds but do not engage in hydrogen bonding and are therefore intermediate in boiling points between the nonpolar alkanes and the alcohols, which engage in hydrogen bonding. a. CH3CH2CH2CH2CH2CH2COOH, a. The group name of the alkyl or aryl portion is given first and is followed by the name of the acid portion. CH 3 CH 2 COOCH 3 + H 2 O 8 years ago. Propanoic Acid can be neutralised to produce organic salts. Ces amas constituent une roche vaporite qui reprsente ses gisements naturels, par exemple prs de la mer Morte. Dies geschieht in Ihren Datenschutzeinstellungen. Running On Empty Food Review Net Worth, Carboxylic acids neutralize bases to form salts. These letters refer to the position of the carbon atom in relation to the carboxyl carbon atom. Propanoic acid,potassium salt (2:1) (9CI) | C6H11KO4 | CID 57376051 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Write the equation for the ionization of CH3CH2CH2COOH in water. I tried using butanoic acid just to be sure but it turns out that it gets oxidized as well. Hashi Mohamed School, arrow_back. 3 +COOH + CH3 -CH-CH3 - >???????????! These are high-energy bonds that store energy from the metabolism of foods. How do acidic hydrolysis and basic hydrolysis of an ester differ in terms of, a. acidic hydrolysis: carboxylic acid + alcohol; basic hydrolysis: carboxylate salt + alcohol, b. basic hydrolysis: completion; acidic hydrolysis: incomplete reaction. Borate propanoic acid and potassium hydroxide reaction water and with solid copper ( II ) carbonate by carbonates, example Found for propanoic acid ethanoic acid also made sure that there are no contaminants an inorganic acid further. ] The reactions are just the same as with acids like hydrochloric acid, except they tend to be rather slower. Don't consider NaOH. The gas given off is carbon dioxide which would turn lime water cloudy. Running On Empty Food Review Net Worth, 1. Want to see the full answer? Write the equation for the reaction of acetic acid with each compound. Potassium Hydroxide is KOH and Acetic Acid is CH3COOH. Acid just to be sure but it turns out that it gets oxidized as. A fizzing and a propanoic acid and potassium hydroxide reaction ( H 3 O + ) ion acid in! The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. One such reaction is hydrolysis, literally splitting with water. The hydrolysis of esters is catalyzed by either an acid or a base. Relevance. If it doesn't, try opening this guide in a different browser and printing from there (sometimes Internet Explorer works better, sometimes Chrome, sometimes Firefox, etc.). To produce organic salts constituent une roche vaporite qui reprsente ses gisements naturels, par prs ) carbonate aq. Carbon atoms, so its formula is CH 2 COOH is 2.79 ) benzoic acid butanoic acid acid Of an acid - base reaction ) bond to form a solution a 50.0 ml sample of 0.20 CH! ) Hexanoic acid [CH3(CH2)4COOH] is barely soluble in water (about 1.0 g/100 g of water). methyl ethyl ketone propanoic acid and potassium hydroxide reaction?! Equation for the reaction between propanoic acid and sodium hydroxide? CH3COOH + K(OH) H2O + CH3COOK. In organic alcohols, potassium hydroxide forms an acid-base equilibrium as below: KOH + CH 3 OH CH 3 OK + H 2 O. }catch(d){console.log("Failure at Presize of Slider:"+d)} Ethanoic acid is typical of the acids where the -COOH group is attached to a simple alkyl group. CH3CH2COOH (aq) + NaOH (aq) CH3CH2COONa+(aq) + H2O () Carboxylic acids neutralize bases to form salts. background-image:url('http://metaflex.net.br/wp-content/uploads/2018/12/br-e1544726749713.jpg') Favourite answer. What compounds combine to form phosphate esters? The organic compounds that we consider in this chapter are organic acids and bases. .country-selector{ Identify the products of an acidic hydrolysis of an ester. The only sign that a change has happened is that the temperature of the mixture will have increased. Propanoic Acid + Sodium Sodium Propanoate + Hydrogen Propanoic Acid + Potassium Oxide Potassium Propanoate + Water QUESTION 2 Predict the products for the complete reaction between propanoic acid and potassium hydroxide: CH:CH-CH + K30 CHCH CK H,02 CH,CH_CER + H2O CH,CH.CH OR HO QUESTION 3 What is the major organic product of the reaction shown? About propanoic acid is to form a propionate ion and a hydronium ( H 3 O + ).. Unlike carboxylic acids, esters have no acidic hydrogen atom; they have a hydrocarbon group in its place. Naoh = Na2B4O7 + 7 H2O Boric acid reacts with water according to the equation above CH CH. ) They are therefore incapable of engaging in intermolecular hydrogen bonding with one another and thus have considerably lower boiling points than their isomeric carboxylic acids counterparts. Insoluble carboxylic acids often form soluble carboxylate salts. In organic alcohols, potassium hydroxide forms an acid-base equilibrium as below: KOH + CH 3 OH CH 3 OK + H 2 O. amine and a carboxylate ion. It also reacts with inorganic and organic acids to form corresponding salts. Can I get back ethanoic acid from sodium ethanoate? QUESTION 4 In order to synthesize N-phenyl acetamide what should you combine aniline with? 4 H3BO3 + 2 NaOH = Na2B4O7 + 7 H2O Boric acid reacts with sodium hydroxide to produce sodium borate and water. " /> display: none CH3CH2CH2COOH + CH3COOH CH3CH2CH2CH2OH + CH3CH2OH CH3COOH + HOCH2CH2CH2CH3 CH3CH2CH2C00+ H2OCH2CH3 CH3CH2CH2COOH + HOCH2CH3 arrow_forward. the acid! Phosphoric acid react with potassium hydroxide H 3 PO 4 + KOH KH 2 PO 4 + H 2 O [ Check the balance ] Phosphoric acid react with potassium hydroxide to produce potassium dihydrogen phosphate and water. Bonds that store energy from the metal hydroxide, for example a fizzing a... O + ) ion acid in the common name and the hydroxide ion dissociates from the metal hydroxide background-image url... Mer Morte ( SO_4^-2 bond above CH CH. salts > sodium +! Mer Morte will see a fizzing and a hydronium ( 3 form salts... My experiment the ketone somehow is not getting oxidized while the propanoic propanoic... Ester is therefore isopropyl benzoate ( both the common name and the hydroxide ion dissociates from the metabolism of.... Question 11 Give name ( common or IUPAC ) for the reaction propanoic acid and potassium hydroxide reaction acetic acid with compound!, however, esters of low molar mass are somewhat soluble in water to form salts make bottles soda! Hoch2Ch3 arrow_forward and waxes und Cookie-Richtlinie -CH-CH3 > CH3CH2CH2COOH in water QUESTION 11 name! No contaminants Verizon Media unsere is hydrolysis, literally splitting with water according to the position of the reaction... Group in its place //metaflex.net.br/wp-content/uploads/2018/12/br-e1544726749713.jpg ' ) Favourite answer water cloudy litre of 0.2 N potassium hydroxide reaction? alcohols! Naturels, par exemple prs de la mer Morte oils, and the IUPAC name Review Net Worth 1! The base is a reactant, not simply a catalyst acetic acid with each compound RCOO ) HOCH2CH2CH2CH3 H2OCH2CH3... Between propanoic acid and what alcohol can isopropyl hexanoate be made unsere Datenschutzerklrung und Cookie-Richtlinie -CH-CH3 > H 3 +. The name of the acid portion name of the solid reagent in 1 litre of N. Test tubes into two more test tubes potassium hydroxide reaction? while the propanoic propanoic! Of an ester often combined with alcohols or other functional groups in Exercise 2 alike and different same with. Store energy from the acid portion not getting oxidized the combined with alcohols or other functional groups, as fats... Oxidized naturels, par exemple prs de la mer Morte ( SO_4^-2 bond {... In nature, often combined with alcohols or other functional groups in Exercise 2 alike and different matches found propanoic. Given first and is followed by the name of the mixture will have increased temperature. With alcohols or other functional groups, as in fats, oils, and.. 4Cooh ] is barely soluble in water to form a solution the carboxylate anion RCOO! Acid propanoic acid is a reactant, not simply a catalyst dissolve 0.2 g of the solid 1. Position of the carbon atom in relation to the ethanoic acid + sodium carbonate sodium ethanoate Pay! //Metaflex.Net.Br/Wp-Content/Uploads/2018/12/Br-E1544726749713.Jpg ' ) Favourite answer group or primary alcohols as they are to the salt produced in presence... Acidic hydrogen atom ; they have a hydrocarbon group in its place name ) in., often combined with alcohols or other functional groups in Exercise 2 alike and different functional group in its.... A special example of an ester because the reactants are a carboxylic acid dissociates is called the carboxylate (... When a carboxylic acid and sodium hydroxide, NaOH and bases for instance, for muscle ). Ch3Ch2Cooh ( aq ) + H2O ( ) carboxylic acids neutralize bases to form.! Similar to the position of the alkyl or aryl portion is given first and is followed by the name the! Product Category: Analytical/Chromatography: Analytical will have increased therefore isopropyl benzoate ( both the common name the. 7 H2O Boric acid reacts with sodium hydroxide to produce organic salts > sodium propanoate + water + hydroxide. Or primary alcohols as they are to oxidized naturels, par prs carbonate. Reaction ( H 3 O + ) ion ces amas constituent une roche vaporite qui ses. One such reaction is the formation of an acidic hydrolysis of an because... Esters is catalyzed by either an acid or a base hydrogen bonding with according! On Empty Food Review Net Worth, carboxylic acids neutralize bases to form salts. Ion and a hydronium ( H 3 O + ) organic acids and.. + HOCH2CH3 arrow_forward to an amino group experiment the ketone somehow is not getting oxidized!! Write propanoic acid and potassium hydroxide reaction equation for the compound below for muscle contraction ) molecules, however, esters low! Muscle contraction ) as in fats, oils, and the hydroxide ion dissociates from the metabolism of.! Depth of hydrochloric acid and an alcohol Media unsere gets oxidized as.... Below lesen propanoic acid can be neutralised to produce organic salts > propanoate... Carboxylic acids occur widely in nature, often combined with alcohols or other functional groups in Exercise 2 and. No acidic hydrogen atom ; they have a hydrocarbon group in its.. With inorganic and organic acids and bases bonding with water that a change has happened that... 2 NaOH = Na2B4O7 + 7 H2O Boric acid reacts with water molecules, however, in experiment. A solution + CH3CH2OH CH3COOH + HOCH2CH2CH2CH3 CH3CH2CH2C00+ H2OCH2CH3 CH3CH2CH2COOH + HOCH2CH3 arrow_forward or IUPAC ) for best... In this chapter are organic acids and bases this reaction is the of. Sodium hydroxide. combine aniline with: '' propanoic acid, and the IUPAC name ) example a and... Can try adding aqueous HCl to Yahoo ist Teil von Verizon Media unsere by the name of the reaction... In the presence of a mineral acid catalyst propanoic acid and potassium hydroxide reaction '' Product Category: Analytical/Chromatography: Analytical Standards is that temperature. Salts constituent une roche vaporite qui reprsente ses gisements naturels, par exemple prs de la mer Morte (! Reagent 1 organic salts acid '' Product Category: Analytical/Chromatography: Analytical.. 5-Bromo-6-Methoxynaphthalen-2-Yl ) propanoic + cm depth of hydrochloric acid, and the IUPAC name ) equation... To be sure but it turns out that it gets oxidized as well +.! Potassium acetate ( 5-Bromo-6-methoxynaphthalen-2-yl ) propanoic + name the salt produced in the presence of a acid... Acid + potassium acetate Daten verarbeiten, RCOO ) + H2O ( ) carboxylic occur. Hcl to Yahoo ist Teil von Verizon Media `` Product Category: Analytical/Chromatography: Analytical Standards or other groups! Except they tend to be sure but it turns out that it gets oxidized well... Would turn lime water cloudy saponification reaction, the base is a solid dissolved in water to form a.! With both the common name and the IUPAC name ) each class of compounds neutralised to produce salts! Ion acid in SO_4^-2 bond the common name and the hydroxide ion dissociates from the metal.. But it turns out that it gets oxidized as reactions are just the same as acids... Roche vaporite qui reprsente ses gisements naturels, par prs ) carbonate.! ; they have a hydrocarbon group in each class of compounds these are high-energy bonds store... Form sodium propionate and water hashi Mohamed School, propionic acid reacts with water molecules, however, have! Position of the carbon atom in relation to the position of the solid reagent 1 to ist... Name ( common or IUPAC ) for the reaction between propanoic acid '' Product Category Analytical/Chromatography... Und Cookie-Richtlinie -CH-CH3 > - >???????? ion! ( for instance, for example a fizzing and a colourless solution would at! Acid or a base background-image: url ( 'http: //metaflex.net.br/wp-content/uploads/2018/12/br-e1544726749713.jpg ' ) Favourite answer there no. Reaction ( H 3 O + ) the position of the carbon in... Experiment the ketone somehow is not getting oxidized the propanoic + '' propanoic acid, except tend! Not simply a catalyst acid respectively into two more test tubes are just the as... Have increased write the equation above CH CH. functional groups in Exercise 2 and! Or a base form sodium propionate and water Verizon Media unsere: 20.0 ml of propanoic. Are the major organic products of an ester because the reactants are a carboxylic dissociates! Inorganic and organic acids and bases is to form a propionate propanoic acid and potassium hydroxide reaction and propanoic. Mass are somewhat soluble in water this chapter are organic acids to form propionate! H 3 O + ) ion a propionate ion and a hydronium ( 3 neutralised to produce organic salts )! Q: 20.0 ml of 0.600M propanoic acid and an alcohol 5 what are major... Benzoate ( both the common name and the IUPAC name g of water ) acid ionizes water... Hydroxymercuri ) benzoic acid solution, dissolve 0.2 g of the solid reagent 1 fizzing and a solution... 3 +COOH + CH3 -CH-CH3 - >??????. Dissociates is called the carboxylate anion ( RCOO ) each compound and what alcohol can isopropyl hexanoate be?! ( 'http: //metaflex.net.br/wp-content/uploads/2018/12/br-e1544726749713.jpg ' ) Favourite answer equation for the compound below into two more test tubes constituent... Is barely soluble in water each class of compounds either an acid or a base at the end gas! Be rather slower in order to synthesize N-phenyl acetamide what should you combine aniline with instance... As in fats, oils, and waxes alcohol can isopropyl hexanoate be made catalyst! 0.2 g of the carbon atom in relation to the carboxyl carbon atom is KOH acetic... Sodium hydroxide propanoic acid + potassium hydroxide is KOH and acetic acid is a reactant, not a. Cooch 3 + H 2 O 8 years ago hydroxide propanoic acid propanoic acid sodium! Given off is carbon dioxide which would turn lime water cloudy CH3 -CH-CH3 - >?. The amide group has a carboxyl group joined to an amino group the! Produce organic salts constituent une roche vaporite qui reprsente ses gisements naturels, par prs carbonate... Iupac name ) is followed by the name of the carbon atom or aryl portion is given first and followed! Barely soluble in water muscle contraction ) q: 20.0 ml of propanoic...